SPEAR MINT

Mentha spicata

Mint / Dead-Nettle Family [Lamiaceae]  

month8jul month8july month8Aug month8sep month8sept month8Oct

status
statusZarchaeophyte
 
flower
flower8lilac
 
morph
morph8zygo
 
petals
petalsZ4
 
type
typeZtieredwhorls
 
type
typeZspiked
 
stem
stem8square
 
smell
smell8spearmint
spearmint

9th Sept 2009, Sandown, IoW. Photo: (CC by 2.0) Geoff Toone
The stems are erect and grow to 90cm high. It usually smells of Spearmint.


9th Sept 2009, Sandown, IoW. Photo: (CC by 2.0) Geoff Toone
Has many whorls of flowers up the top part of the stem, the lower ones more separated than the tightly knit topmost whorls.


9th Sept 2009, Sandown, IoW. Photo: (CC by 2.0) Geoff Toone
Leaves not usually rugose (meaning slightly wrinkled), but sometimes remarkably rugose with deep 'ravines' as in this specimen from Sandown. It can be either hairless (as here) or hairy.


10th Sept 2007, Leeds & Liverpool Canal, Burscough Bridge Photo: © RWD
Whereas these specimens from Burscough Bridge are hairy.


10th Sept 2007, Leeds & Liverpool Canal, Burscough Bridge Photo: © RWD
It is either not branched or has but few branches.


10th Sept 2007, Leeds & Liverpool Canal, Burscough Bridge Photo: © RWD
The leaves are usually without stalks, as here, but may have very short ones instead.


10th Sept 2007, Leeds & Liverpool Canal, Burscough Bridge Photo: © RWD


10th Sept 2007, Leeds & Liverpool Canal, Burscough Bridge Photo: © RWD
The upper whorls of flowers have short narrow bracts just below the whorl. Can be hairy or glabrous; these specimens hairy. The leaf teeth are rather pointed but not long and point forwards and between 1 to 3mm long.


10th Sept 2007, Leeds & Liverpool Canal, Burscough Bridge Photo: © RWD
The leaves on this specimen are only slightly rugose.


10th Sept 2007, Leeds & Liverpool Canal, Burscough Bridge Photo: © RWD


10th Sept 2007, Leeds & Liverpool Canal, Burscough Bridge Photo: © RWD


10th Sept 2007, Leeds & Liverpool Canal, Burscough Bridge Photo: © RWD
The calyx has 4 petals which are white to pink or lilac (as here) and is bell-shaped and has teeth which are narrowly-triangular to narrow-linear with an abrupt triamgular ending [here narrowly-triangular].


Not to be semantically confused with Spear-Leaved Orache (Atriplex prostrata), Spear Thistle (Cirsium vulgare), Spear-leaved Willowherb (Epilobium lanceolatum), Greater Spearwort (Ranunculus lingua), Lesser Spearwort (Ranunculus flammula) or Adder's-tongue Spearwort (Ranunculus ophioglossifolius) [plants from disparate families with similar names].

Hybridizes with :

Some similarities to other mints.

Spearmint can exist as two or more Chemotypes, where exactly the same species of plant can produce differing secondary metabolites, which might depend upon the region it is growing in or on environmental factors. This is why sometimes it instead does not smell of spearmint.

It is an Archaeophyte of the denizen type - meaning that it can compete with already established vegetation like a native plant usually does. It is widely grown then naturalised in waste or rough ground.

It is a tetraploid, meaning it has 4 sets of identical chromosomes and it is a product of the hybrid between Horse Mint (Mentha longifolia) [which does not grow in the UK] and Round-Leaved Mint (Mentha Suaveolens) and can have characteristics almost anywhere between those two Mints.

Easily confused with : Horse Mint (Mentha longifolia) (but that doesn't grow in the UK)...

It is used to produce the well-known spearmint taste/smell in sweets (which is due to the presence of Carvone), such as Wriglys' Spearmints.

MONOTERPENE KETONES

The chemical, Carvone, a typical terpene, is the main active ingredient (67 - 80%) in oil of spearmint) prepared by distillation of the leaves from Spear Mint. It is used in chewing gum and some toothpastes (other toothpastes might use oil of peppermint, or menthol).



Carvone exists in two different stereoisomers which smell completely different to each other. The first, (R)-Carvone is the one found in Spearmint and Corn Mint and smells of peppermint; whereas (S)-Carvone is found in Caraway and smells accordingly.

With animals (and all other creatures) being constructed from chiral molecules, it is then perhaps no surprise that another chiral molecule (Carvone in this instance), smells completely differently depending upon which chiral form, (R)-Carvone, or (S)-Carvone, is presented to the smell sensors. This is not a unique occurrence; many molecules work completely differently in humans (and other creatures) depending on the exact stereoisometric form present. Sometimes one stereoisometric form will work as intended whilst the other form is toxic.


Pulgenone (not to be confused with Pulegone, which it resembles chemically, but the two are not identical) is used as a flavouring agent, its mild toxicity being of no concern at the low concentrations required, being less than 1/10,000th of the toxic dose. In the body it is metabolized to Menthofuran, shown below, which is 10 times as toxic as Pulgenone, but still of no safety concern. Pulgenone occurs in greater concentration in Pennyroyal, and has been implicated in human Pennyroyal poisoning in those un-able to metabolize Pulgenone into Menthofuran. The only difference between Pulgenone and Menthol below is the C=C double bond in Pulgenone which is a single bond in Menthone.

Menthone is another, but minor, constituent of Spearmint, Peppermint and Pelargonium geraniums. Although it can exist in four different stereoisometric configurations, it is the (2S, 5R)-trans- enantiomer that is the most frequent in nature. Structurally, it is related to Menthol, and has a similar minty and aromatic smell and finds use in perfumes.

The essential oil also contains 13-20% Limonene, 7% Eucalyptol, 2% Pulgenone (the main constituent of Pennyroyal) and 0.2% Menthone. It also contains α-Pinene, β-Pinene, Camphene, Carvacrol, Eugenol, Furfural, β-Ionone, Menthofuran, Caryophyllene, Jasmone and many other minor constituents.

Further aromatic compounds found in Spearmint oil

Menthofuran is also used as a flavouring agent, its toxicity being of no concern at the low concentrations required, being less than 1/1000th of the toxic dose. Menthofuran in higher concentrations can damage the liver, it is hepatotoxic, and high consumption of Pennyroyal can be harmful, especially to women.

Ionones such as β-Ionone are so-called Rose Ketones so named because they are found in essential oils of Roses, as well as in the essential oils of some other plants. [Rose ketones not found within Spearmint include α-Ionone, γ-Ionone, β-Damascone, β-Damascenone, all of which smell fragrantly (in slightly differing ways) of rose petals and all are used in perfumery]. The Carotenes α-carotene, β-carotene, γ-carotene, Xanthophyll and β-CryptoXanthin all contain at one or both ends a molecule of β-Ionone. Indeed, β-Ionone is a degradation product of the Carotenoids α-Carotene, β-Carotene, γ-carotene and from the Xanthophyll-β-Cryptoxanthin. Because β-Ionone can be converted to Retinol within the stomach of animals, all these carotenoids possess Vitamin A activity. But not all carotenoids have a molecule of β-Ionone at one or both ends, and cannot therefore all be converted into Retinol nor into Retinal, and therefore not all carotenoids exhibit Vitamin A activity.

Jasmone is another aldehyde more typically found in Jasmine flowers, but also present in Spearmint. It has the fragrance of Jasmine and is used in perfumes. Exists in two isomers, cis- and trans-Jasmone (both of which smell similarly) it is produced in plants from the Jasmonates such as Jasmonic Acid and Methyl Jasmonate which are a group of plant hormones. Jasmone can act as a pheromone to various insects, either as an attractant or a repellent. In plants Jasmone is derived from Linolenic acid.

Furfural is a toxic aldehyde with the odour of almonds but is in no way related to another much more toxic chemical that also smells of (bitter) almonds: Hydrocyanic Acid. It is occasionally used in perfume. On exposure to air it turns yellow. It is manufactured commercially from Oat hulls but can also be obtained using a chemical process from other brans, corn cobs and from sawdust. It is an irritant to the skin and chronic exposure to the substance can lead to skin allergy and hyper-susceptibility to sunburn. It occurs in many foods but usually at sub-toxic concentrations. Compare Furfural with Tulipalin A.

It is Spearmint rather than Peppermint (Water Mint) which flavours the World famous Kendal Mint Cake.


  Mentha spicata  ⇐ Global Aspect ⇒ Lamiaceae  

Distribution
family8mint family8Dead-Nettle family8Labiatea family8Lamiaceae
 BSBI maps
genus8Mentha
Mentha
(Mints)

SPEAR MINT

Mentha spicata

Mint / Dead-Nettle Family [Lamiaceae]  

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